REACTION OF A VANADIUM(III) AMIDE WITH H-2 - ISOLATION AND CHARACTERIZATION OF A POLYNUCLEAR MIXED-VALENCE POLYHYDRIDO-NITRIDO COMPLEX

被引：69

作者：

BERNO, P

GAMBAROTTA, S

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa, Ontario

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 07期

关键词：

COMPLEXES WITH HYDRIDE LIGANDS; COMPLEXES WITH NITRIDO LIGANDS; VANADIUM COMPOUNDS;

D O I：

10.1002/anie.199508221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complex 2 is formed by two discrete ions which originate during hydrogenolysis of 1 according to Equation (a). The cation is dinuclear with three bridging hydrido ligands. The mixed‐valent anion of 2 is also dinuclear and contains two bridging nitrido moieties, which cannot be the product of the hydrogenolysis of NSi bonds since silanes are not formed in the reaction. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：822 / 824

页数：3

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