REACTIVITY OF A 4-MEMBERED VANADACYCLE RING SUPPORTED BY BULKY SILAZANATE - REGIOSELECTIVE HYDROGENATION OF PYRIDINE

被引：37

作者：

BERNO, P ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear {[(Me3Si)2N]V[mu-N(SiMe3)-Si(Me2CH2]}2 complex, containing a four-membered metallacyclic ring, has been obtained via reaction of VCl3(THF)3 with (Me3Si)2NLi. The reactivity of the metallacycle has been investigated with respect to the coordination of bases, hydrogenation, and insertion of alkynes.

引用

收藏

页码：2569 / 2571

页数：3

相关论文

共 40 条

[1] 3-COORDINATED TRANSITION-METAL COMPOUNDS .2. ELECTRONIC-SPECTRA AND MAGNETISM OF TRIS(BISTRIMETHYLSILYLAMIDO)DERIVATIVES OF SCANDIUM, TITANIUM, VANADIUM, CHROMIUM, AND IRON [J].

ALYEA, EC ;

BRADLEY, DC ;

COPPERTH.RG ;

SALES, KD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (02) :185-191

[2] 3-COORDINATED TRANSITION-METAL COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF TRIS(BISTRIMETHYLSILYLAMIDO)-DERIVATIVES OF SCANDIUM, TITANIUM, VANADIUM, CHROMIUM, AND IRON [J].

ALYEA, EC ;

BRADLEY, DC ;

COPPERTHWAITE, RG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (14) :1580-+

[3] SYNTHESIS OF BIS[BIS(TRIMETHYLSILYL)AMIDO]IRON(II) - STRUCTURE AND BONDING IN MN[N(SIME3)2]2, FE[N(SIME3)2]2, CO[N(SIME3)2]2 - 2-COORDINATE TRANSITION-METAL AMIDES [J].

ANDERSEN, RA ;

FAEGRI, K ;

GREEN, JC ;

HAALAND, A ;

LAPPERT, MF ;

LEUNG, WP ;

RYPDAL, K .

INORGANIC CHEMISTRY, 1988, 27 (10) :1782-1786

[4] PREPARATION OF THE BIS(TRIMETHYLSILYL)AMIDO LANTHANIDE CHLORIDES [(LN[N(SIME3)2]2(MU-CL)(TETRAHYDROFURAN))2], AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF THE GADOLINIUM AND YTTERBIUM COMPLEXES [J].

ASPINALL, HC ;

BRADLEY, DC ;

HURSTHOUSE, MB ;

SALES, KD ;

WALKER, NPC ;

HUSSAIN, B .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :623-626

[5]

ASPINALL HC, 1988, J CHEM SOC DA, P2211

[6]

Bartlett R.A., 1989, ANGEW CHEM, V101, P325

[7] PREPARATION, CHARACTERIZATION, AND REACTIVITY OF THE BINUCLEAR VANADIUM(III) COMPOUND ([(ME3SI)2N]V[MU-CH2SIME2N(SIME3)])2 - C-H SIGMA-BOND METATHESIS PROMOTED BY AN AMIDO FUNCTION [J].

BERNO, P ;

MINHAS, R ;

HAO, SK ;

GAMBAROTTA, S .

ORGANOMETALLICS, 1994, 13 (04) :1052-1054

[8] TRIS(N,N'-DIMETHYLETHYLENEDIAMINATO)DIMOLYBDENUM AND TRIS(N,N'-DIMETHYLETHYLENEDIAMINATO)DITUNGSTEN - A COMPARISON OF ECLIPSED AND STAGGERED TRIPLE BONDS, SIGMA-2 PI-4, BETWEEN MOLYBDENUM AND TUNGSTEN ATOMS IN X3M=MX3 COMPOUNDS [J].

BLATCHFORD, TP ;

CHISHOLM, MH ;

HUFFMAN, JC .

INORGANIC CHEMISTRY, 1987, 26 (12) :1920-1925

[9]

Bradley D. C., 1978, INORG SYNTH, P112

[10] CRYSTAL MOLECULAR-STRUCTURE OF BIS(HEXAMETHYLDISILYLAMIDO) MANGANESE [J].

BRADLEY, DC ;

HURSTHOUSE, MB ;

MALIK, KMA ;

MOSELER, R .

TRANSITION METAL CHEMISTRY, 1978, 3 (04) :253-254

← 1 2 3 4 →