REACTIVITY OF A 4-MEMBERED VANADACYCLE RING SUPPORTED BY BULKY SILAZANATE - REGIOSELECTIVE HYDROGENATION OF PYRIDINE

被引：37

作者：

BERNO, P ^{[1
]}

GAMBAROTTA, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear {[(Me3Si)2N]V[mu-N(SiMe3)-Si(Me2CH2]}2 complex, containing a four-membered metallacyclic ring, has been obtained via reaction of VCl3(THF)3 with (Me3Si)2NLi. The reactivity of the metallacycle has been investigated with respect to the coordination of bases, hydrogenation, and insertion of alkynes.

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页码：2569 / 2571

页数：3

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