Optical alignment and patterning of nanoscale microdomains in a block copolymer thin film

被引:211
作者
Morikawa, Y
Nagano, S
Watanabe, K
Kamata, K
Iyoda, T
Seki, T [1 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan
[2] Tokyo Inst Technol, Chem Resources Lab, CREST, Yokohama, Kanagawa 2268503, Japan
关键词
D O I
10.1002/adma.200502573
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Optical 3D alignment of nanocylinders has been successfully attained for thin films of a block copolymer (see figure) comprising azobenzene-containing liquid-crystalline polymers and poly(ethylene oxide) via photoinduced massive migration. ne out-of-plane and inplane alignments are achieved by controlling the film thickness and selection of linear polarization direction upon illumination, respectively.
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页码:883 / +
页数:5
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