Fabrication of porous tin by template-free electrodeposition of tin nanowires from an ionic liquid

被引：21

作者：

Deng, Ming-Jay ^{[1
]}

Leong, Tin-Iao ^{[1
]}

Sun, I. -Wen ^{[1
]}

Chen, Po-Yu ^{[3
]}

Chang, Jeng-Kuei ^{[2
]}

Tsai, Wen-Ta ^{[2
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

[2] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan

[3] Kaohsiung Med Univ, Fac Med & Appl Chem, Kaohsiung, Taiwan

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2008年 / 11卷 / 11期

关键词：

D O I：

10.1149/1.2978089

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Direct electrodeposition of macroporous tin is achieved in a water- and air-stable room-temperature ionic liquid, namely, 1-ethyl-3-methylimidazolium-dicyanamide. This is the first example showing that tin nanowires interweaving into a porous structure can be obtained in ionic liquid without using any additive and template. The nanostructures, with great uniformity, high porosity, and good adhesion, were prepared by galvanostatic deposition at a current ranging from 0.3 to 1.2 mA cm(-2). Electrodeposition experiments performed in the 1-ethyl-3-methylimidazoliun-tetrafluoro borate ionic liquid under a similar condition generated granular tin rather than tin wires. (C) 2008 The Electrochemical Society.

引用

页码：D85 / D88

页数：4

共 28 条

[1] Electrodeposition of zinc-tin alloys from deep eutectic solvents based on choline chloride [J].

Abbott, Andrew P. ;

Capper, Glen ;

McKenzie, Katy J. ;

Ryder, Karl S. .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 599 (02) :288-294

[2] Mesoporous platinum films from lyotropic liquid crystalline phases [J].

Attard, GS ;

Bartlett, PN ;

Coleman, NRB ;

Elliott, JM ;

Owen, JR ;

Wang, JH .

SCIENCE, 1997, 278 (5339) :838-840

[3] Surface characterization of Li-modified platinum/tin catalysts for isobutane dehydrogenation [J].

Casella, ML ;

Siri, GJ ;

Santori, GF ;

Ferretti, OA ;

Ramírez-Corredores, MM .

LANGMUIR, 2000, 16 (13) :5639-5643

[4] Electrochemical study of copper in a basic 1-ethyl-3-methylimidazolium tetrafluoroborate room temperature molten salt [J].

Chen, PY ;

Sun, IW .

ELECTROCHIMICA ACTA, 1999, 45 (03) :441-450

[5] Dicyanamide anion based ionic liquids for electrodeposition of metals [J].

Deng, Ming-Jay ;

Chen, Po-Yu ;

Leong, Tin-Iao ;

Sun, I-Wen ;

Chang, Jeng-Kuei ;

Tsai, Wen-Ta .

ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (02) :213-216

[6] Nanoporous metals with controlled multimodal pore size distribution [J].

Ding, Y ;

Erlebacher, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) :7772-7773

[7] Electrodeposition of nano- and microcrystalline aluminium in three different air and water stable ionic liquids [J].

El Abedin, S. Zein ;

Moustafa, E. M. ;

Hempelmann, R. ;

Natter, H. ;

Endres, F. .

CHEMPHYSCHEM, 2006, 7 (07) :1535-1543

[8] On the electrodeposition of titanium in ionic liquids [J].

Endres, F. ;

El Abedin, S. Zein ;

Saad, A. Y. ;

Moustafa, E. M. ;

Borissenko, N. ;

Price, W. E. ;

Wallace, G. G. ;

MacFarlane, D. R. ;

Newman, P. J. ;

Bund, A. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (16) :2189-2199

[9]

Endres F., 2008, ELECTRODEPOSITION IO

[10] Metal nanowires and intercalated metal layers in single-walled carbon nanotube bundles [J].

Govindaraj, A ;

Satishkumar, BC ;

Nath, M ;

Rao, CNR .

CHEMISTRY OF MATERIALS, 2000, 12 (01) :202-205

← 1 2 3 →