Fabrication of porous tin by template-free electrodeposition of tin nanowires from an ionic liquid

被引：21

作者：

Deng, Ming-Jay ^{[1
]}

Leong, Tin-Iao ^{[1
]}

Sun, I. -Wen ^{[1
]}

Chen, Po-Yu ^{[3
]}

Chang, Jeng-Kuei ^{[2
]}

Tsai, Wen-Ta ^{[2
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

[2] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan

[3] Kaohsiung Med Univ, Fac Med & Appl Chem, Kaohsiung, Taiwan

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2008年 / 11卷 / 11期

关键词：

D O I：

10.1149/1.2978089

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Direct electrodeposition of macroporous tin is achieved in a water- and air-stable room-temperature ionic liquid, namely, 1-ethyl-3-methylimidazolium-dicyanamide. This is the first example showing that tin nanowires interweaving into a porous structure can be obtained in ionic liquid without using any additive and template. The nanostructures, with great uniformity, high porosity, and good adhesion, were prepared by galvanostatic deposition at a current ranging from 0.3 to 1.2 mA cm(-2). Electrodeposition experiments performed in the 1-ethyl-3-methylimidazoliun-tetrafluoro borate ionic liquid under a similar condition generated granular tin rather than tin wires. (C) 2008 The Electrochemical Society.

引用

页码：D85 / D88

页数：4

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