A polymer-bound chiral template for enantioselective photochemical reactions

被引：27

作者：

Breitenlechner, Stefan ^{[1
]}

Bach, Thorsten ^{[1
]}

机构：

[1] Tech Univ Munich, Lehrstuhl Organ Chem 1, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 41期

关键词：

cycloaddition; enantioselectivity; photochemistry; polymers; solid-phase synthesis;

D O I：

10.1002/anie.200802479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A happy couple: A chiral complexing agent was modified with an ω-hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7957 / 7959

页数：3

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