Magnetic properties of γ-Fe2O3-SiO2 aerogel and xerogel nanocomposite materials

被引:70
作者
Cannas, C
Casula, MF
Concas, G
Corrias, A
Gatteschi, D
Falqui, A
Musinu, A
Sangregorio, C
Spano, G
机构
[1] Univ Cagliari, Dipartimento Sci Chim, I-09042 Cagliari, Italy
[2] Univ Cagliari, Dipartimento Fis, I-09042 Cagliari, Italy
[3] Ist Nazl Fis Mat, I-09042 Cagliari, Italy
[4] Univ Florence, Dipartimento Chim, I-50144 Florence, Italy
关键词
D O I
10.1039/b104562h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties of aerogel and xerogel iron oxide-silica nanocomposites prepared by the sol-gel method were investigated by thermal analysis, X-ray diffraction, transmission electron microscopy, Mossbauer spectroscopy and susceptibility measurements. Pure maghemite nanoparticles were obtained starting from both xerogel and aerogel samples, with particles of average size around 5 nm which tend to aggregate into the silica matrix. The role of magnetic interparticle interactions, which have a strong influence on the magnetic properties, is discussed.
引用
收藏
页码:3180 / 3187
页数:8
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