Catalysis using multifunctional organosiliceous hybrid materials

被引:223
作者
Diaz, Urbano [1 ]
Brunel, Daniel [1 ,2 ]
Corma, Avelino [1 ]
机构
[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, E-46022 Valencia, Spain
[2] UM1, ENSCM, UM2, CNRS,UMR 5253,Inst Gerhardt,Ecole Natl Super Chim, F-34296 Montpellier 05, France
关键词
PERIODIC MESOPOROUS ORGANOSILICAS; ISOCYANURATE BRIDGING GROUPS; ORGANIC-INORGANIC MATERIALS; ONE-POT; FUNCTIONAL-GROUPS; HETEROGENEOUS CATALYSIS; COOPERATIVE CATALYSIS; CASCADE REACTIONS; POROUS MATERIALS; TERTIARY-AMINES;
D O I
10.1039/c2cs35385g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic-inorganic hybrid materials with different levels of structuration and porous hierarchy and one or several types of active sites in the framework can catalyze multistep chemical processes in a one-pot reactor system following a cascade of reaction events. It will show how the different active sites can act in a synergistic or in a consecutive way following a similar functionality model to biological multisite catalysts. Research on this subject for heterogeneous catalysts is still in the beginning stage and very interesting results can be expected if we are able to successfully combine the properties of organic and inorganic catalysts.
引用
收藏
页码:4083 / 4097
页数:15
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