Hypervalent iodine/TEMPO-mediated oxidation in flow systems: a fast and efficient protocol for alcohol oxidation

被引：20

作者：

Ambreen, Nida ^{[1
]}

Kumar, Ravi ^{[1
]}

Wirth, Thomas ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷

基金：

英国工程与自然科学研究理事会;

关键词：

alcohols; carbonyl compounds; flow chemistry; microreactor; oxidation; ALPHA-AMINO-ACIDS; VERSATILE; REAGENTS; CATALYST; ALDEHYDES; SCOPE;

D O I：

10.3762/bjoc.9.162

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hypervalent iodine(III)/TEMPO-mediated oxidation of various aliphatic, aromatic and allylic alcohols to their corresponding carbonyl compounds was successfully achieved by using microreactor technology. This method can be used as an alternative for the oxidation of various alcohols achieving excellent yields and selectivities in significantly shortened reaction times.

引用

页码：1437 / 1442

页数：6

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