Supramolecular chiral recognition by bischlorins: A two-point interaction mode combined with the host's conformational modulation controlled by the guest's stereochemistry and bulkiness
被引:17
作者:
Borovkov, Victor V.
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机构:
ICORP, Entropy Control Project, JST, Osaka 5600085, JapanICORP, Entropy Control Project, JST, Osaka 5600085, Japan
Borovkov, Victor V.
[1
]
Inoue, Yoshihisa
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ICORP, Entropy Control Project, JST, Osaka 5600085, JapanICORP, Entropy Control Project, JST, Osaka 5600085, Japan
Inoue, Yoshihisa
[1
]
机构:
[1] ICORP, Entropy Control Project, JST, Osaka 5600085, Japan
Supramolecular chiral recognition based on two-point host-guest interactions coupled with the different host's conformational response using the enantiopure bischlorin hosts and different antipodal amine guests is reported. The bulkiness at the guest's stereogenic center controls the chiral recognition properties resulting in switching of the enantioselectivity.