Supramolecular chiral recognition by bischlorins: A two-point interaction mode combined with the host's conformational modulation controlled by the guest's stereochemistry and bulkiness

被引:17
作者
Borovkov, Victor V. [1 ]
Inoue, Yoshihisa [1 ]
机构
[1] ICORP, Entropy Control Project, JST, Osaka 5600085, Japan
关键词
D O I
10.1021/ol060649u
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Supramolecular chiral recognition based on two-point host-guest interactions coupled with the different host's conformational response using the enantiopure bischlorin hosts and different antipodal amine guests is reported. The bulkiness at the guest's stereogenic center controls the chiral recognition properties resulting in switching of the enantioselectivity.
引用
收藏
页码:2337 / 2340
页数:4
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