Electrochemistry as a correlation tool with the catalytic activities in [RuCl2(p-cymene)(PAr3)]-catalysed Kharasch additions

被引：42

作者：

Richel, A ^{[1
]}

Demonceau, A ^{[1
]}

Noels, AF ^{[1
]}

机构：

[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Liege, Belgium

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 13期

关键词：

catalysis; electrochemistry; olefins; radicals and radical reactions; ruthenium and compounds;

D O I：

10.1016/j.tetlet.2006.01.138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[RuCl2(p-cymene)] complexes containing triarylphosphine ligands with various substituents at the para position were used to catalyse the atom transfer radical addition of carbon tetrachloride to various olefins, and their catalytic activities were nicely correlated with their electrochemical parameters. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2077 / 2081

页数：5

共 42 条

[1] ROLE AND EFFECTS OF HALIDE-IONS ON THE RATES AND MECHANISMS OF OXIDATIVE ADDITION OF IODOBENZENE TO LOW-LIGATED ZEROVALENT PALLADIUM COMPLEXES PD0(PPH3)2
AMATORE, C
AZZABI, M
JUTAND, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) : 8375 - 8384
[2] Use of QALE to generate potential energy surfaces in transition states:: associative reactions of Ru3(CO)12 with P-donor nucleophiles
Babij, C
Chen, HW
Chen, LZ
Poë, AJ
[J]. DALTON TRANSACTIONS, 2003, (16) : 3184 - 3191
[3] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE
BENNETT, MA
SMITH, AK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (02): : 233 - 241
[4] LIGAND ELECTRONIC EFFECTS IN ASYMMETRIC CATALYSIS - ENHANCED ENANTIOSELECTIVITY IN THE ASYMMETRIC HYDROCYANATION OF VINYLARENES
CASALNUOVO, AL
RAJANBABU, TV
AYERS, TA
WARREN, TH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) : 9869 - 9882
[5] Atom transfer radical cyclisation reactions mediated by copper complexes
Clark, AJ
[J]. CHEMICAL SOCIETY REVIEWS, 2002, 31 (01) : 1 - 11
[6] Delaude L, 2004, TOP ORGANOMETAL CHEM, V11, P155
[7] Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP
Delaude, L
Delfosse, S
Richel, A
Demonceau, A
Noels, AF
[J]. CHEMICAL COMMUNICATIONS, 2003, (13) : 1526 - 1527
[8] RESOLUTION OF CPMO(NO)X(ETA-3-2-METHALLYL) COMPLEXES AND THEIR ENANTIOSELECTIVE REACTIONS WITH AN ALDEHYDE
FALLER, JW
NGUYEN, JT
ELLIS, W
MAZZIERI, MR
[J]. ORGANOMETALLICS, 1993, 12 (04) : 1434 - 1438
[9] Diaminoarylnickel(II) "pincer" complexes: Mechanistic considerations in the Kharasch addition reaction, controlled polymerization, and dendrimeric transition metal catalysts
Gossage, RA
Van De Kuil, LA
Van Koten, G
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) : 423 - 431
[10] Metal-catalyzed living radical polymerization
Kamigaito, M
Ando, T
Sawamoto, M
[J]. CHEMICAL REVIEWS, 2001, 101 (12) : 3689 - 3745

← 1 2 3 4 5 →