Electrochemistry as a correlation tool with the catalytic activities in [RuCl2(p-cymene)(PAr3)]-catalysed Kharasch additions

被引：42

作者：

Richel, A ^{[1
]}

Demonceau, A ^{[1
]}

Noels, AF ^{[1
]}

机构：

[1] Univ Liege, Macromol Chem & Organ Catalysis Lab, B-4000 Liege, Belgium

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 13期

关键词：

catalysis; electrochemistry; olefins; radicals and radical reactions; ruthenium and compounds;

D O I：

10.1016/j.tetlet.2006.01.138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[RuCl2(p-cymene)] complexes containing triarylphosphine ligands with various substituents at the para position were used to catalyse the atom transfer radical addition of carbon tetrachloride to various olefins, and their catalytic activities were nicely correlated with their electrochemical parameters. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2077 / 2081

页数：5