CO2-Responsive Nanofibrous Membranes with Switchable Oil/Water Wettability

被引:367
作者
Che, Hailong [1 ]
Huo, Meng [1 ]
Peng, Liao [1 ]
Fang, Tommy [1 ]
Liu, Na [2 ]
Feng, Lin [2 ]
Wei, Yen [2 ]
Yuan, Jinying [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon dioxide; electrospinning; oil/water separation; stimuli-responsive materials; surface chemistry; OIL; SEPARATION; SURFACES; CHEMISTRY; RELEASE;
D O I
10.1002/anie.201501034
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Responsive polymer interfacial materials are ideal candidates for controlling surface wetting behavior. Here we developed smart nanostructured electrospun polymer membranes which are capable of switching oil/water wettability using CO2 as the trigger. In particular, the combination of CO2-responsiveness and porous nanostructure enables the as-prepared membranes to be used as a novel oil/water on-off switch. We anticipate that the promising versatility and simplicity of this system would not only open up a new way of surface wettability change regulation by gas, but also have obvious advantages in terms of highly controlled oil/water separation and CO2 applications.
引用
收藏
页码:8934 / 8938
页数:5
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