Simultaneous Gas Storage and Catalytic Gas Production Using Zeolites-A New Concept for Extending Lifetime Gas Delivery

被引：20

作者：

Boes, Astrid-Karla ^{[1
]}

Xiao, Bo ^{[1
]}

Megson, Ian L. ^{[2
]}

Morris, Russell E. ^{[1
]}

机构：

[1] Univ St Andrews, EaStChem Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Highlands and Islands, Free Rad Res Facil, Inverness IV2 3BL, Scotland

来源：

TOPICS IN CATALYSIS | 2009年 / 52卷 / 1-2期

关键词：

Nitric Oxide; Copper; Catalysis; Cu-MCM-41; NITRIC-OXIDE; MOLECULAR-SIEVES; S-NITROSOTHIOLS; COATED STENTS; MCM-41; ADSORPTION; GENERATION; NO; CYSTEINE; ACIDITY;

D O I：

10.1007/s11244-008-9137-5

中图分类号：

O69 [应用化学];

学科分类号：

070301 [无机化学];

摘要：

Copper containing MCM-41 materials can be used to both store gaseous nitric oxide and to catalytically produce nitric oxide from nitrite. The active species for the reaction is copper (I). Addition of cysteine to the solution in contact with the material has different effects depending on how much Cu(I) is present. This is a new method of extending the lifetime of gas delivery from a gas storage material.

引用

页码：35 / 41

页数：7

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