Influence of different branched alkyl side chains on the properties of imidazolium-based ionic liquids

被引：115

作者：

Erdmenger, Tina ^{[1
,2
]}

Vitz, Juergen ^{[1
,2
]}

Wiesbrock, Frank ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands

[3] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2008年 / 18卷 / 43期

关键词：

D O I：

10.1039/b807119e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several new branched ionic liquids were synthesized under microwave irradiation applying two different synthetic approaches. Different already known ionic liquids, both linear and branched, were added to this set of new ionic liquids to investigate the influence of the branching on the thermophysical properties to elucidate first structure-property relationships. Thermogravimetric analysis was utilized to investigate the decomposition behavior and differential scanning calorimetry was used to study the influence of the branching on the thermal behavior, e. g. the melting point, the glass transition temperature, the freezing point and the cold crystallization temperature. Moreover, the water uptake of selected ionic liquids was analyzed.

引用

页码：5267 / 5273

页数：7

共 42 条

[11] PREPARATION OF 1-BUTYL-3-METHYLIMIDAZOLIUM TETRAFLUOROBORATE [1H-Imidazolium, 1-butyl-3-methyl, tetrafluoroborate (1-)]
Creary, Xavier
Willis, Elizabeth D.
[J]. ORGANIC SYNTHESES, 2005, 82 : 166 - +
[12] Improved preparations of ionic liquids using microwave irradiation
Deetlefs, M
Seddon, KR
[J]. GREEN CHEMISTRY, 2003, 5 (02) : 181 - 186
[13] Homogeneous tritylation of cellulose in 1-butyl-3-methylimidazolium chloride
Erdmenger, Tina
Haensch, Claudia
Hoogenboom, Richard
Schubert, Ulrich S.
[J]. MACROMOLECULAR BIOSCIENCE, 2007, 7 (04) : 440 - 445
[14] Thermophysical properties of imidazolium-based ionic liquids
Fredlake, CP
Crosthwaite, JM
Hert, DG
Aki, SNVK
Brennecke, JF
[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04) : 954 - 964
[15] New chiral imidazolinic derivatives
Génisson, Y
Lauth-de Viguerie, N
André, C
Baltas, M
Gorrichon, L
[J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (05) : 1017 - 1023
[16] Protic ionic liquids: Properties and applications
Greaves, Tamar L.
Drummond, Calum J.
[J]. CHEMICAL REVIEWS, 2008, 108 (01) : 206 - 237
[17] Many protic ionic liquids mediate hydrocarbon-solvent interactions and promote amphiphile self-assembly
Greaves, Tamar L.
Weerawardena, Asoka
Fong, Celesta
Drummond, Calum J.
[J]. LANGMUIR, 2007, 23 (02) : 402 - 404
[18] Protic ionic liquids: Solvents with tunable phase behavior and physicochemical properties
Greaves, Tamar L.
Weerawardena, Asoka
Fong, Celesta
Krodkiewska, Irena
Drummond, Calum J.
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (45) : 22479 - 22487
[19] Fast and "green" living cationic ring opening polymerization of 2-ethyl-2-oxazoline in ionic liquids under microwave irradiation
Guerrero-Sanchez, Carlos
Hoogenboom, Richard
Schubert, Ulrich S.
[J]. CHEMICAL COMMUNICATIONS, 2006, (36) : 3797 - 3799
[20] Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation
Huddleston, JG
Visser, AE
Reichert, WM
Willauer, HD
Broker, GA
Rogers, RD
[J]. GREEN CHEMISTRY, 2001, 3 (04) : 156 - 164

← 1 2 3 4 5 →