Spectroelectrochemical characterization of aniline/metanilic acid copolymers

被引:12
作者
Bernard, MC [1 ]
Joiret, S [1 ]
Hugot Le Goff, A [1 ]
机构
[1] UPMC, UPR 15, CNRS, Tour 22,Pl Jussieu 4, F-75252 Paris 05, France
关键词
iron; polyaniline; copolymer; Raman spectroscopy; optical spectroscopy;
D O I
10.1023/B:RUEL.0000019659.63033.41
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Films of aniline/metanilic acid copolymers ensure a better protection of iron against corrosion with respect to the protection given by polyaniline. Raman and optical spectroscopies are used to characterize this new material. The confrontation with the polyaniline properties allows to understand the improvement of protection.
引用
收藏
页码:235 / 244
页数:10
相关论文
共 25 条
[1]   Protection of iron against corrosion using a polyaniline layer - II. Spectroscopic analysis of the layer grown in phosphoric/metanilic solution [J].
Bernard, MC ;
Joiret, S ;
Hugot-Le Goff, A ;
Long, PD .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :B299-B303
[2]   In situ Raman study of sulfonate-doped polyaniline [J].
Bernard, MC ;
de Torresi, SC ;
Hugot-Le Goff, A .
ELECTROCHIMICA ACTA, 1999, 44 (12) :1989-1997
[3]   Protection of iron against corrosion using a polyaniline layer - III. Spectroscopic analysis of the mechanisms accompanying the breakdown [J].
Bernard, MC ;
Joiret, S ;
Hugot-Le Goff, A ;
Phong, PV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (08) :B304-B306
[4]   Protection of iron against corrosion using a polyaniline layer I. Polyaniline electrodeposit [J].
Bernard, MC ;
Joiret, S ;
Hugot-Le Goff, A ;
Phong, PV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :B12-B16
[5]   ELECTROCHROMIC PHENOMENA IN POLYANILINE FILMS - EFFECT OF PH AND INFLUENCE OF THE SWEEP RANGE ON CYCLING LIFETIMES STUDIED BY INSITU RAMAN-SPECTROSCOPY [J].
BERNARD, MC ;
CORDOBATORRESI, S ;
HUGOTLEGOFF, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1992, 25 (3-4) :225-240
[6]   RRS characterization of selected oligomers of polyaniline in situ spectroelectrochemical study [J].
Boyer, MI ;
Quillard, S ;
Cochet, M ;
Louarn, G ;
Lefrant, S .
ELECTROCHIMICA ACTA, 1999, 44 (12) :1981-1987
[7]  
Cochet M, 2000, J RAMAN SPECTROSC, V31, P1041, DOI 10.1002/1097-4555(200012)31:12<1041::AID-JRS641>3.0.CO
[8]  
2-R
[9]  
da Silva JEP, 2000, MACROMOLECULES, V33, P3077
[10]   MODIFICATION OF THE ELECTROCHEMICAL AND CORROSION BEHAVIOR OF STAINLESS-STEELS WITH AN ELECTROACTIVE COATING [J].
DEBERRY, DW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (05) :1022-1026