Battery Electrolytes Based on Unsaturated Ring Ionic Liquids: Conductivity and Electrochemical Stability

被引：18

作者：

DiLeo, Roberta A. ^{[1
,2
]}

Marschilok, Amy C. ^{[1
,2
]}

Takeuchi, Kenneth J. ^{[1
]}

Takeuchi, Esther S. ^{[1
,2
,3
]}

机构：

[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA

[2] SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11794 USA

[3] Brookhaven Natl Lab, Global & Reg Solut, Upton, NY 11973 USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2013年 / 160卷 / 09期

关键词：

CATHODE MATERIALS; ALKYL CHAIN; LITHIUM; CARBONATE; VISCOSITY; SOLVENT;

D O I：

10.1149/2.045309jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Physical and electrochemical properties of electrolytes prepared from ionic liquids in combination with carbonate solvents were measured. Cation, anion, and substituent chain length effects on electrical conductivity were observed, where higher conductivities were observed with imidazolium cations, tetrafluoroborate (BF4-) anions, and shorter chain length substituents, while lower conductivities were observed with pyridinium cations, bis(trifluoromethanesulfonyl) imide (TFSI-) anions, and longer chain length substituents. High voltage stability was demonstrated by the ionic liquid based mixtures, where the majority of the mixtures demonstrated voltage stability at >= 5 V, and some demonstrated stability at >= 6 V. The development and optimization of new ionic liquid battery electrolyte systems have the potential to improve realizable energy density and safety of lithium ion battery systems. (C) 2013 The Electrochemical Society.

引用

页码：A1399 / A1405

页数：7

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