Hydrothermal synthesis of carbon nanotube/cubic Fe3O4 nanocomposite for enhanced performance supercapacitor electrode material

被引：192

作者：

Guan, Dahui ^{[1
]}

Gao, Zan ^{[1
]}

Yang, Wanlu ^{[1
]}

Wang, Jun ^{[1
,2
]}

Yuan, Yao ^{[1
]}

Wang, Bin ^{[1
]}

Zhang, Milin ^{[1
,2
]}

Liu, Lianhe ^{[1
,2
]}

机构：

[1] Harbin Engn Univ, Minist Educ, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Peoples R China

[2] Harbin Engn Univ, Inst Adv Marine Mat, Harbin 150001, Peoples R China

来源：

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2013年 / 178卷 / 10期

关键词：

Carbon nanotube; Iron oxide; Composite material; Supercapacitor; METAL-ION BINDING; MANGANESE-DIOXIDE; GRAPHENE; COMPOSITE; ENERGY; FUNCTIONALIZATION; NANOPARTICLES; MECHANISM; GROWTH; FILMS;

D O I：

10.1016/j.mseb.2013.03.010

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Carbon nanotube/Fe3O4 (CNT/Fe3O4) nanocomposite with well-dispersed Fe3O4 nano-cubes inlaid on the surfaces of carbon nanotubes, was synthesized through an easy and efficient hydrothermal method. The electrochemical behaviors of the nanocomposite were analyzed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and chronopotentiometry in 6 M KOH electrolyte. Results demonstrated that CNT as the supporting material could significantly improve the supercapacitor (SC) performance of the CNT/Fe3O4 composite. Comparing with pure Fe3O4, the resulting composite exhibited improved specific capacitances of 117.2 F/g at 10 mA/cm(2) (3 times than that of pure Fe3O4), excellent cyclic stability and a maximum energy density of 16.2 Wh/kg. The much improved electrochemical performances could be attributed to the good conductivity of CNTs as well as the anchored Fe3O4 particles on the CNTs. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：736 / 743

页数：8

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