An organic photoelectrode working in the water phase: Visible-light-induced dioxygen evolution by a perylene derivative/cobalt phthalocyanine bilayer

被引：100

作者：

Abe, T ^{[1
]}

Nagai, K

Kabutomori, S

Kaneko, M

Tajiri, A

Noritnatsit, T

机构：

[1] Hirosaki Univ, Dept Mat Sci & Technol, Hirosaki, Aomori 0368561, Japan

[2] Osaka Univ, ILE, Suita, Osaka 5650871, Japan

[3] Ibaraki Univ, Fac Sci, Mito, Ibaraki 3108512, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 17期

关键词：

dioxygen evolution; photocatalysis; photoelectrochemistry; phthalocyanines; semiconductors;

D O I：

10.1002/anie.200504454

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Two layers are better than one: The organic bilayer composed of 3,4,9,10-perylenetetracarboxylic acid bisbenzimidazole (PTCBI, an n-type semiconductor) and cobalt phthalocyanine (CoPc, a p-type semiconductor) was found to act as a novel photoanode that is responsive to visible light under 750 nm to induce efficiently the photoelectrochemical splitting of water to evolve dioxygen. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2778 / 2781

页数：4

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