Structure and function revealed with submolecular resolution at the liquid-solid interface

被引：57

作者：

Elemans, Johannes A. A. W.

De Feyter, Steven ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, Div Mol & Nanomat, B-3001 Louvain, Belgium

来源：

SOFT MATTER | 2009年 / 5卷 / 04期

关键词：

SCANNING-TUNNELING-MICROSCOPY; ASSEMBLED SUPRAMOLECULAR RECTANGLE; 2-DIMENSIONAL MOLECULAR NETWORK; SOLVENT-INDUCED POLYMORPHISM; SELECTIVE GUEST INCLUSION; AU(111) SURFACES; SELF-ORGANIZATION; TRIMESIC ACID; GRAPHITE SURFACE; NEAT LIQUID;

D O I：

10.1039/b811090e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The liquid-solid interface is a unique medium to support the self-assembly of molecules into surface-confined networks. Non-covalent interactions are key in forming these two-dimensional (2D) architectures, and a deep understanding is crucial for successful 2D crystal engineering. Scanning tunnelling microscopy is the tool of choice to reveal the structure and function of these patterns with subnanometre resolution. A recent success is the formation of 2D nanoporous molecular patterns and their host guest chemistry. However, this is not the only functionality addressed by this review. Surface-confined molecular architectures at the liquid solid interface are also relevant in the field of molecular electronics. Furthermore, inducing and probing chemical reactivity at the single-molecule level at the liquid solid interface might turn out to be one of the most exciting developments.

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收藏

页码：721 / 735

页数：15

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