A supramolecular approach to the crystallization of polynuclear aqua ions: Structure and magnetism of an 18-crown-6 adduct of bis(mu-hydroxo)octaaquadichromium(III) mesitylene-2-sulfonate trihydrate

被引：20

作者：

Drljaca, A ^{[1
]}

Hockless, DCR ^{[1
]}

Moubaraki, B ^{[1
]}

Murray, KS ^{[1
]}

Spiccia, L ^{[1
]}

机构：

[1] MONASH UNIV,DEPT CHEM,CLAYTON,VIC 3168,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 10期

关键词：

D O I：

10.1021/ic9614125

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular approach to the crystallization of polynuclear aqua ions has been developed which utilizes the ability of the donor atoms of macrocyclic ligands, such as 18-crown-6, to hydrogen-bond to coordinated water molecules, thereby modifying the 3D II-bonding network that surrounds such ions in aqueous solution. The synthesis, X-ray structure, and magnetic properties of [Cr-2(mu-OH)(2)(H2O)(8)][(H3C)(3)C6H2SO3](4) . C12H24O6 . 3H(2)O are reported.

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页码：1988 / &

页数：3

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