Room-temperature Cannizzaro reaction under mild conditions facilitated by magnesium bromide ethyl etherate and triethylamine

被引：48

作者：

Abaee, MS ^{[1
]}

Sharifi, R ^{[1
]}

Mojtahedi, MM ^{[1
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, Organ Chem Lab, Tehran, Iran

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 26期

关键词：

D O I：

10.1021/ol052506y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A room-temperature convenient Cannizzaro reaction prompted by magnesium bromide ethyl etherate and triethylamine is described for smooth conversion of aromatic aldehydes into their respective alcohols, and carboxylic acids. The methodology is applicable to both inter- and intramolecular reactions and could be directed to obtain the carboxylic moiety in the form of an acid, an amide, or an ester compound depending on the selected reaction conditions or workup procedure.

引用

页码：5893 / 5895

页数：3

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