Allenyls and propargyls: versatile ligands in ransition-metal chemistry

被引：66

作者：

Wojcicki, A ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

关键词：

allenyl complexes; propargyl complexes; binuclear complexes; trinuclear complexes; mixed-metal complexes; synthesis;

D O I：

10.1016/S1387-7003(01)00343-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mononuclear. binuclear, and trinuclear transition-metal allenyl and/or propargyl complexes are reviewed with respect to methods of synthesis, structure, and reaction chemistry. Structural relationships among the various types of complexes are presented and, to the extent possible, used to rationalize some patterns of reactivity. Recent developments in the field are accorded special emphasis. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：82 / 97

页数：16

相关论文

共 135 条

[1] SYNTHESIS OF DICARBONYL(ETA-5-CYCLOPENTADIENYL)(ETA-1-2-METHOXYALLYL)IRON - REACTION WITH TETRACYANOETHYLENE AND FORMATION OF A CYCLOPENTANE ACETAL [J].

ABRAM, TS ;

BAKER, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (06) :267-268

[2] Reaction of isocyanides with [(PPh3)2Pt(η3-CH2CCPh)]+ and the formation of the indenyl complex trans-[(PPh3)2Pt(η1-1H-inden-2-yl) (CNC(CH3)3)]+ [J].

Ackermann, MN ;

Ajmera, RK ;

Barnes, HE ;

Gallucci, JC ;

Wojcicki, A .

ORGANOMETALLICS, 1999, 18 (04) :787-792

[3]

AIME S, 1983, POLYHEDRON, V2, P77, DOI 10.1016/S0277-5387(00)84676-8

[4]

ANDRIANOV VG, 1978, KOORDINATS KHIM, V4, P298

[5] STUDIES ON AN IRON-SIGMA-PROPARGYL COMPLEX [J].

ARIYARATNE, JKP ;

GREEN, MLH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1963, 1 (01) :90-93

[6] REACTION OF [P(C6H5)4][FE2(CO)6(MU-CO)(MU-CHCH2)] WITH [RHCL(CO)2]2 - SYNTHESIS OF A TRIIRON-DIRHODIUM CLUSTER ANION CONTAINING A CH3C=C=CH2 TRIIRON-DIRHODIUM LIGAND WITH AN UNUSUAL MU-4-ETA-3 MODE OF BONDING, [P(C6H5)4][FE3RH2(CO)10(MU-CO)3(MU-4-ETA-3-CH3C=C=CH2)] [J].

ATTALI, S ;

DAHAN, F ;

MATHIEU, R .

ORGANOMETALLICS, 1986, 5 (07) :1376-1379

[7] CHEMISTRY OF PI-COMPLEXES DERIVED FROM [(PH3P)2PT-(ETA-3-CH2CCPH)](O3SCF3) - INTERCONVERSION BETWEEN ETA-3-ALKOXOALLYL AND ETA-3-OXOALLYL COMPLEXES AND BETWEEN ETA-3-AMINOALLYL AND ETA-IMINOALLYL COMPLEXES [J].

BAIZE, MW ;

FURILLA, JL ;

WOJCICKI, A .

INORGANICA CHIMICA ACTA, 1994, 223 (1-2) :1-4

[8] eta(3)-Propargyl/allenyl complexes of platinum and palladium of the type [(PPh(3))(2)M(eta(3)-CH(2)CCR)](+) [J].

Baize, MW ;

Blosser, PW ;

Plantevin, V ;

Schimpff, DG ;

Gallucci, JC ;

Wojcicki, A .

ORGANOMETALLICS, 1996, 15 (01) :164-173

[9] CRYSTAL AND MOLECULAR-STRUCTURE OF (MU-ETA-2,ETA-3-PROPARGYL)BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM TETRAFLUOROBORATE AND (MU-ETA-2,ETA-3-1,1-DIMETHYLPROPARGYL)BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM TETRAFLUOROBORATE [J].

BARINOV, IV ;

REUTOV, OA ;

POLYAKOV, AV ;

YANOVSKY, AI ;

STRUCHKOV, YT ;

SOKOLOV, VI .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 418 (02) :C24-C27

[10] Asymmetric benzopentaannulation from tungsten ((-)-menthyloxy)(aryl)carbene complexes, alkynyllithiums, and methyl triflate [J].

Barluenga, J ;

Trabanco, AA ;

Flórez, J ;

García-Granda, S ;

Llorca, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :12129-12130

← 1 2 3 4 5 6 7 8 9 10 →