Allenyls and propargyls: versatile ligands in ransition-metal chemistry

被引：66

作者：

Wojcicki, A ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

关键词：

allenyl complexes; propargyl complexes; binuclear complexes; trinuclear complexes; mixed-metal complexes; synthesis;

D O I：

10.1016/S1387-7003(01)00343-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mononuclear. binuclear, and trinuclear transition-metal allenyl and/or propargyl complexes are reviewed with respect to methods of synthesis, structure, and reaction chemistry. Structural relationships among the various types of complexes are presented and, to the extent possible, used to rationalize some patterns of reactivity. Recent developments in the field are accorded special emphasis. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：82 / 97

页数：16

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