Asymmetric total synthesis of syringolide 1, a nonproteinaceous elicitor

被引：20

作者：

Ishihara, J ^{[1
]}

Sugimoto, T ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,GRAD SCH SCI,DIV CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON | 1997年 / 53卷 / 47期

关键词：

D O I：

10.1016/S0040-4020(97)10062-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An asymmetric synthesis of syringolide 1, one of the elicitors produced by Pseudomonas syringae pv. tomato, is described. It was synthesized from 2-(1-oxoethyl)-2-buten-4-olide via 1,4-addition of alkenyl cuprate, asymmetric dihydroxylation, and intramoleculr Michael reaction. (C) 1997 Elsevier Science Ltd.

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页码：16029 / 16040

页数：12

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