Comb-shaped polymers to enhance hydroxide transport in anion exchange membranes

被引:390
作者
Li, Nanwen [1 ]
Yan, Tingzi [2 ]
Li, Zheng [1 ]
Thurn-Albrecht, Thomas [2 ]
Binder, Wolfgang H. [1 ]
机构
[1] Univ Halle Wittenberg, Fac Nat Sci Chem Phys & Math 2, Div Tech & Macromol Chem, Inst Chem,Chair Macromol Chem, D-06120 Halle, Germany
[2] Univ Halle Wittenberg, Fac Nat Sci Chem Phys & Math 2, Inst Phys, D-06120 Halle, Germany
关键词
POLYELECTROLYTE-SURFACTANT COMPLEXES; ALKALINE FUEL-CELLS; PERFORMANCE; TEMPERATURE; IONOMER; GRAFT; STATE;
D O I
10.1039/c2ee22050d
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Comb-shaped poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) polymers with quaternary ammonium (QA) groups have been synthesized organizing into well-defined micro-morphology for efficient anion (hydroxide) transport. These molecular comb structures show a dramatic enhancement in conductivity and water resistance compared with non-comb-shaped PPOs.
引用
收藏
页码:7888 / 7892
页数:5
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