[Cr(Salen)] as a 'bridge' between asymmetric catalysis, Lewis acids and redox processes

被引：120

作者：

Bandini, M ^{[1
]}

Cozzi, PG ^{[1
]}

Umani-Ronchi, A ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 09期

关键词：

D O I：

10.1039/b109945k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview focused on the synthesis, structural features and catalytic applications of chiral [Cr(Salen)] complexes is presented. Key aspects of modern organic chemistry such as Lewis acids, asymmetric catalysis and redox processes are strictly connected with chronium-Schiff base complexes. Among the asymmetric transformations mediated by [Cr(Salen)] complexes, Diels-Alder and hetero-Diels-Alder reactions, ARO of epoxides, kinetic resolution of meso-epoxides and Nozki-Hyama reactions are taken into account.

引用

页码：919 / 927

页数：9

共 107 条

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