Polymer-supported cobalt (II) catalysts for the oxidation of alkenes

被引：36

作者：

Blaz, E ^{[1
]}

Pielichowski, J ^{[1
]}

机构：

[1] Krakow Univ Technol, Dept Polymer Sci & Technol, PL-31155 Krakow, Poland

来源：

MOLECULES | 2006年 / 11卷 / 01期

关键词：

epoxidation; cobalt complexes; polyaniline based-catalysts; conjugated-polymers; catalysts;

D O I：

10.3390/11010115

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Polymer-supported heterogeneous catalysts in a form of complexes of 8-hydroxyquinoline with cobalt acetate were synthesized. Conjugated polymers-polyaniline (PANI), poly-o-toluidine (POT), poly-o-anisidine (POA) - were used as supports. Oxidation reactions of aliphatic and aromatic hydrocarbons were carried out in the presence of molecular oxygen at atmospheric pressure and epoxides or ketones were obtained as the main products with high selectivity.

引用

页码：115 / 120

页数：6

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