A NOVEL REDOX SYSTEM FOR THE PALLADIUM(II)-CATALYZED OXIDATION BASED ON REDOX OF POLYANILINES

被引：58

作者：

HIRAO, T

HIGUCHI, M

HATANO, B

IKEDA, I

机构：

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 33期

关键词：

D O I：

10.1016/0040-4039(95)01143-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A complex system consisting of palladium(ll) acetate and polyaniline derivatives permitted the catalytic Wacker oxidation, indicating that polyanilines serve as a ligand with reversible redox capability under oxygen atmosphere, Substitution on the phenyl ring and protonic acid doping of polyanilines were found to affect the catalytic activity.

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页码：5925 / 5928

页数：4

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