Topochemical polymerization of 1-naphthylmethylammonium sorbate and characterization of the resulting stereoregular polymer

被引：13

作者：

Matsumoto, A ^{[1
]}

Odani, T ^{[1
]}

机构：

[1] Osaka City Univ, Fac Engn, Dept Appl Chem, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

POLYMER JOURNAL | 1999年 / 31卷 / 09期

关键词：

topochemical reaction; solid-state photopolymerization; sorbic acid derivative; controlled polymerization; diene monomer; stereoregularity;

D O I：

10.1295/polymj.31.717

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photoreaction of alkylammonium sorbates was examined in the crystalline state. The crystals of the 1-naphthylmethylammonium salt or sorbic acid provide an insoluble and crystalline polymer under UV irradiation. This polymer is converted to the water-soluble polymers by the solid-state transformation and consist of a tritactic structure, indicating that the polymerization proceeds under the crystal lattice control. The topochemical polymerization of 1,3-diene compounds proceeds not only for muconic acid derivatives but also sorbic acid derivatives.

引用

页码：717 / 719

页数：3

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