Topochemical polymerization of 1-naphthylmethylammonium sorbate and characterization of the resulting stereoregular polymer

被引：13

作者：

Matsumoto, A ^{[1
]}

Odani, T ^{[1
]}

机构：

[1] Osaka City Univ, Fac Engn, Dept Appl Chem, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

POLYMER JOURNAL | 1999年 / 31卷 / 09期

关键词：

topochemical reaction; solid-state photopolymerization; sorbic acid derivative; controlled polymerization; diene monomer; stereoregularity;

D O I：

10.1295/polymj.31.717

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photoreaction of alkylammonium sorbates was examined in the crystalline state. The crystals of the 1-naphthylmethylammonium salt or sorbic acid provide an insoluble and crystalline polymer under UV irradiation. This polymer is converted to the water-soluble polymers by the solid-state transformation and consist of a tritactic structure, indicating that the polymerization proceeds under the crystal lattice control. The topochemical polymerization of 1,3-diene compounds proceeds not only for muconic acid derivatives but also sorbic acid derivatives.

引用

页码：717 / 719

页数：3

共 19 条

[11]

2-P

[12] STEREOSPECIFIC POLYMERIZATION OF DIETHYL (Z,Z)-HEXA-2,4-DIENEDIOATE IN THE CRYSTALLINE STATE [J].

MATSUMOTO, A ;

MATSUMURA, T ;

AOKI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (11) :1389-1390

[13]

MATSUMOTO A, IN PRESS POLYM PREPR, V40

[14]

ODANI T, UNPUB

[15]

PALCOS M, 1992, POLYM ORG MEDIA

[16] Winogradsky discovered a new Modus vivendi [J].

Schlegel, HG .

ANAEROBE, 1996, 2 (03) :129-136

[17]

STUPP SI, 1999, SYNTHESIS POLYM, P513

[18] SOLID-STATE POLYMERIZATION OF BUTADIENES - POLYMERIZATION OF SALTS OF "6-AMINO-2,4-TRANS,TRANS-HEXADIENOIC ACID [J].

TIEKE, B .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (02) :391-406

[19]

TIEKE B, 1985, ADV POLYM SCI, V71, P79

← 1 2 →