Synthesis of borasiloxane-based macrocycles by multicomponent condensation reactions in solution or in a ball mill

被引：63

作者：

Pascu, Mirela ^{[1
]}

Ruggi, Albert ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 01期

基金：

瑞士国家科学基金会;

关键词：

BORON; ACID; DERIVATIVES; CRYSTAL; FACILE; AMINES; CAGES; RING;

D O I：

10.1039/c2cc37538a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large macrocycles containing imine and borasiloxane links are obtained in polycondensation reactions of 4-formylbenzeneboronic acid, t-Bu2Si(OH)(2), and diamines. The multicomponent reactions can be performed in solution or - advantageously - by mechanochemical syntheses in a ball mill.

引用

页码：45 / 47

页数：3

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