An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (Sparteine)PdCl2

被引：57

作者：

Trend, RM ^{[1
]}

Stoltz, BM ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 14期

关键词：

D O I：

10.1021/ja039551q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A model for asymmetric induction in palladium-catalyzed aerobic oxidative kinetic resolution is described. The model is based on coordination complexes and general reactivity trends of the parent (sp)PdCl2 catalyst. The first example of a nonracemic chiral palladium alkoxide complex is presented, and exhibits the subtle steric influences of the C1symmetric ligand sparteine. Copyright © 2004 American Chemical Society.

引用

页码：4482 / 4483

页数：2

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