Chemistry of silyl thioketones .9. A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size.

被引：19

作者：

Bonini, BF

ComesFranchini, M

Fochi, M

Mazzanti, G

Ricci, A

机构：

[1] Dipto. di Chim. Organica A. Mangini, Fac. di Chimica Industriale, 40136 Bologna

来源：

TETRAHEDRON | 1996年 / 52卷 / 13期

关键词：

D O I：

10.1016/0040-4020(96)00148-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

omega-Haloacylsilanes 1 were selectively transformed via thioacylsilanes into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or into 2-silylthiacycloalk-2-ene 5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.

引用

页码：4803 / 4816

页数：14

共 25 条

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