New microporous coordination polymer affording guest-coordination sites at channel walls

被引：142

作者：

Noro, S

Kitagawa, S ^{[1
]}

Yamashita, M

Wada, T

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Sakyo Ku, Kyoto 6068501, Japan

[2] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan

[3] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b108695b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Utilization of a metalloligand, {[Cu(2,4-pydca)(2) (H2O)].2Et(3)NH} (1) (2,4-pydca = pyridine-2,4-dicarboxylate), as a building unit provides a novel porous coordination polymer, {[ZnCu(2,4-pydca) 2(H2O)(3)(DMF)].DMF}(n) (2), in which the Zn(II) ion at the node of the network acts as a linker and the Cu(II) ion in the channel wall is available for guest-coordination.

引用

页码：222 / 223

页数：2