Tertiary amine-accelerated allylgallation of terminal alkynes

被引：17

作者：

Takai, K ^{[1
]}

Ikawa, Y ^{[1
]}

Ishii, K ^{[1
]}

Kumanda, M ^{[1
]}

机构：

[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 02期

关键词：

D O I：

10.1246/cl.2002.172

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylic gallium sesquibromides prepared by reduction of allylic bromides with gallium metal in the presence of a catalytic amount of indium, add to terminal alkynes with the aid of a tertiary amine to give 1,4-dienes.

引用

页码：172 / 173

页数：2

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