STEREOSELECTIVE SYNTHESIS OF POLYSUBSTITUTED OLEFINS VIA THE FORMATION OF 1,1-BIMETALLOALKENES

被引：14

作者：

CRETON, I ^{[1
]}

MAREK, I ^{[1
]}

NORMANT, JF ^{[1
]}

机构：

[1] UNIV PARIS 06,CNRS,CHIM ORGANOELEMENTS LAB,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 41期

关键词：

ALLYLMETALLATION; 1,1-BIMETALLOALKENES; CARBENOIDS; 1,2-METALATE REARRANGEMENT;

D O I：

10.1016/0040-4039(95)01551-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoselective reaction of 1,1-bimetalloalkenes with different electrophiles allows the synthesis of the corresponding polysubstituted olefins

引用

页码：7451 / 7454

页数：4

共 52 条

[1] PLANAR TETRACOORDINATE CARBON STABILIZED IN A DIMETALLIC HAFNIUM ALUMINUM COMPOUND - FORMATION AND CRYSTAL-STRUCTURE OF CP2HF[MU-ETA-1 ETA-2-MECC(C6H11)][MU-CC(C6H11)]ALME2 [J].

ALBRECHT, M ;

ERKER, G ;

NOLTE, M ;

KRUGER, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (03) :C21-C25

[2] THE HYDROALUMINATION OF OMEGA-TERBUTOXY ALKYNES - AN EASY ACCESS TO OMEGA-HYDROXY ALKENYL IODIDES - APPLICATION TO THE SYNTHESIS OF DIENIC INSECT PHEROMONES [J].

ALEXAKIS, A ;

DUFFAULT, JM .

TETRAHEDRON LETTERS, 1988, 29 (48) :6243-6246

[3] UNUSUAL 1,2-MIGRATION IN ORGANOALUMINUM CHEMISTRY, PROMOTED BY BF3.0ET2 [J].

ALEXAKIS, A ;

HANAIZI, J ;

JACHIET, D ;

NORMANT, JF ;

TOUPET, L .

TETRAHEDRON LETTERS, 1990, 31 (09) :1271-1274

[4] 1,2-METALLATE REARRANGEMENTS OF ALPHA-ALKOXYVINYL BORATES [J].

BIRKINSHAW, S ;

KOCIENSKI, P .

TETRAHEDRON LETTERS, 1991, 32 (47) :6961-6964

[5]

BONNET B, 1993, SYNTHESIS-STUTTGART, P1071

[6] PHEROMONES VIA ORGANOBORANES .2. VINYLIC ORGANOBORANES .8. APPLICATIONS OF THE GENERAL STEREOSELECTIVE SYNTHESIS OF (E)-DISUBSTITUTED ALKENES VIA THEXYLCHLOROBORANE-DIMETHYL SULFIDE TO THE SYNTHESIS OF PHEROMONES CONTAINING AN (E)-ALKENE MOIET [J].

BROWN, HC ;

LEE, HD ;

KULKARNI, SU .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (26) :5282-5286

[7] VINYLIC ORGANOBORANES .6. A GENERAL-SYNTHESIS OF (E)-DISUBSTITUTED ALKENES OR KETONES VIA THE (E)-(1-SUBSTITUTED-1-ALKENYL)BORONIC ESTERS [J].

BROWN, HC ;

BASAVAIAH, D ;

KULKARNI, SU ;

LEE, HD ;

NEGISHI, E ;

KATZ, JJ .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (26) :5270-5276

[8]

CHEMLA F, 1993, SYNLETT, P665

[9] BORON-ACTIVATION OF ACETYLENES TO NUCLEOPHILIC-ADDITION REACTIONS [J].

COOKE, MP .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (11) :2930-2931

[10] PHENYLTHIOACETYLENE AS A SOURCE OF STEREODEFINED TRISUBSTITUTED ALKENES [J].

CRETON, I ;

MAREK, I ;

BRASSEUR, D ;

JESTIN, JL ;

NORMANT, JF .

TETRAHEDRON LETTERS, 1994, 35 (37) :6873-6876

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