STEREOSELECTIVE SYNTHESIS OF POLYSUBSTITUTED OLEFINS VIA THE FORMATION OF 1,1-BIMETALLOALKENES

被引：14

作者：

CRETON, I ^{[1
]}

MAREK, I ^{[1
]}

NORMANT, JF ^{[1
]}

机构：

[1] UNIV PARIS 06,CNRS,CHIM ORGANOELEMENTS LAB,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 41期

关键词：

ALLYLMETALLATION; 1,1-BIMETALLOALKENES; CARBENOIDS; 1,2-METALATE REARRANGEMENT;

D O I：

10.1016/0040-4039(95)01551-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoselective reaction of 1,1-bimetalloalkenes with different electrophiles allows the synthesis of the corresponding polysubstituted olefins

引用

页码：7451 / 7454

页数：4

共 52 条

[21] A CONVENIENT METHOD FOR THE STEREOSPECIFIC SYNTHESIS OF (E)-3-ALKEN-1-OLS UTILIZING THE RING-OPENING REACTION OF 2,3-DIHYDROFURAN WITH ORGANOCUPRATES [J].

FUJISAWA, T ;

KURITA, Y ;

KAWASHIMA, M ;

SATO, T .

CHEMISTRY LETTERS, 1982, (10) :1641-1642

[22]

GAUDEMAR M, 1971, CR ACAD SCI C CHIM, V273, P1669

[23] SELECTIVE DEBROMINATION OF 1,1-DIBROMOALKENES - A NEW ACCESS TO DISUBSTITUTED OR TRISUBSTITUTED ALKENES [J].

GRANDJEAN, D ;

PALE, P .

TETRAHEDRON LETTERS, 1993, 34 (07) :1155-1158

[24] REACTIONS OF 1,1-DIHALOALKENES WITH TRIORGANOZINCATES - A NOVEL METHOD FOR THE PREPARATION OF ALKENYLZINC SPECIES ASSOCIATED WITH CARBON-CARBON BOND FORMATION [J].

HARADA, T ;

KATSUHIRA, T ;

HARA, D ;

KOTANI, Y ;

MAEJIMA, K ;

KAJI, R ;

OKU, A .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (18) :4897-4907

[25] STEREOCHEMISTRY IN CARBENOID FORMATION BY BROMINE LITHIUM AND BROMINE ZINC EXCHANGE-REACTIONS OF 1,1-DIBROMOALKENES - HIGHER REACTIVITY OF THE STERICALLY MORE HINDERED BROMINE ATOM [J].

HARADA, T ;

KATSUHIRA, T ;

OKU, A .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (22) :5805-5807

[26]

HILL CM, 1954, J AM CHEM SOC, V76, P4538

[27] PREPARATION OF POLYFUNCTIONAL NITRILES BY THE CYANATION OF FUNCTIONALIZED ORGANOZINC HALIDES WITH P-TOLUENESULFONYL CYANIDE [J].

KLEMENT, I ;

LENNICK, K ;

TUCKER, CE ;

KNOCHEL, P .

TETRAHEDRON LETTERS, 1993, 34 (29) :4623-4626

[28]

KOCIENSKI P, 1993, ORGANIC SYNTHESIS VI, P203

[29] DIASTEREOSELECTIVE CARBOMETALATION OF VINYLMETALS [J].

MAREK, I ;

LEFRANCOIS, JM ;

NORMANT, JF .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (15) :4154-4161

[30]

MAREK I, 1994, B SOC CHIM FR, V131, P910

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