PREPARATION OF POLYFUNCTIONAL NITRILES BY THE CYANATION OF FUNCTIONALIZED ORGANOZINC HALIDES WITH P-TOLUENESULFONYL CYANIDE

被引：61

作者：

KLEMENT, I ^{[1
]}

LENNICK, K ^{[1
]}

TUCKER, CE ^{[1
]}

KNOCHEL, P ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)60640-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various alkyl, alkenyl, alkynyl, benzylic, aromatic or heterocyclic organozinc halides bearing functional groups such as an ester, a boronic ester, a cyanide, a halide or a trialkoxysilyl group react under mild conditions with p-toluenesulfonyl cyanide affording polyfunctional nitriles in 69-93 % yields.

引用

页码：4623 / 4626

页数：4

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