Direct conversion of methane into oxygenates

被引:232
作者
Otsuka, K [1 ]
Wang, Y
机构
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
[2] Xiamen Univ, Inst Phys Chem, Dept Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
关键词
methane; oxygenates; methanol; catalytic conversion; partial oxidation; reductive activation of oxygen; iron phosphate; peroxide;
D O I
10.1016/S0926-860X(01)00837-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Direct conversion of methane into useful chemicals remains as a big challenge in catalysis in the 21st century. A large number of studies have contributed to the direct conversion of methane in the past decade. Although there is still no direct process with commercial viability at this moment, many new methods and catalysts have been developed for the direct activation and conversion of methane. This review highlights the recent novel approaches to the partial oxidation of methane into useful oxygenates with an emphasis on the selective formation of methanol in the presence of H-2. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:145 / 161
页数:17
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