Direct conversion of methane into oxygenates

被引:232
作者
Otsuka, K [1 ]
Wang, Y
机构
[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
[2] Xiamen Univ, Inst Phys Chem, Dept Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
关键词
methane; oxygenates; methanol; catalytic conversion; partial oxidation; reductive activation of oxygen; iron phosphate; peroxide;
D O I
10.1016/S0926-860X(01)00837-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Direct conversion of methane into useful chemicals remains as a big challenge in catalysis in the 21st century. A large number of studies have contributed to the direct conversion of methane in the past decade. Although there is still no direct process with commercial viability at this moment, many new methods and catalysts have been developed for the direct activation and conversion of methane. This review highlights the recent novel approaches to the partial oxidation of methane into useful oxygenates with an emphasis on the selective formation of methanol in the presence of H-2. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:145 / 161
页数:17
相关论文
共 135 条
[91]   Generation of active oxygen species on solid surfaces. Opportunity for novel oxidation technologies over zeolites [J].
Panov, GI ;
Uriarte, AK ;
Rodkin, MA ;
Sobolev, VI .
CATALYSIS TODAY, 1998, 41 (04) :365-385
[92]   NATURAL-GAS CONVERSION TO LIQUID FUELS AND CHEMICALS - WHERE DOES IT STAND [J].
PARKYNS, ND ;
WARBURTON, CI ;
WILSON, JD .
CATALYSIS TODAY, 1993, 18 (04) :385-442
[93]   NOVEL HIGH-ACTIVITY CATALYSTS FOR PARTIAL OXIDATION OF METHANE TO FORMALDEHYDE [J].
PARMALIANA, A ;
FRUSTERI, F ;
MEZZAPICA, A ;
SCURRELL, MS ;
GIORDANO, N .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (09) :751-753
[94]   Synthesis of methyl formate via two-step methane partial oxidation [J].
Parmaliana, A ;
Frusteri, F ;
Arena, F ;
Mezzapica, A ;
Sokolovskii, V .
CATALYSIS TODAY, 1998, 46 (2-3) :117-125
[95]   Platinum catalysts for the high-yield oxidation of methane to a methanol derivative [J].
Periana, RA ;
Taube, DJ ;
Gamble, S ;
Taube, H ;
Satoh, T ;
Fujii, H .
SCIENCE, 1998, 280 (5363) :560-564
[96]   A MERCURY-CATALYZED, HIGH-YIELD SYSTEM FOR THE OXIDATION OF METHANE TO METHANOL [J].
PERIANA, RA ;
TAUBE, DJ ;
EVITT, ER ;
LOFFLER, DG ;
WENTRCEK, PR ;
VOSS, G ;
MASUDA, T .
SCIENCE, 1993, 259 (5093) :340-343
[97]   PARTIAL OXIDATION OF METHANE [J].
PITCHAI, R ;
KLIER, K .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1986, 28 (01) :13-88
[98]   Direct conversion of methane to methanol [J].
Raja, R ;
Ratnasamy, P .
APPLIED CATALYSIS A-GENERAL, 1997, 158 (1-2) :L7-L15
[99]  
ROTH JF, 1994, APPL CATAL A-GEN, V113, P131, DOI 10.1016/0926-860X(94)80021-9
[100]   Vanadium-molybdenum phosphates supported by TiO2-anatase as new catalysts for selective oxidation of ethane to acetic acid [J].
Roy, M ;
GubelmannBonneau, M ;
Ponceblanc, H ;
Volta, JC .
CATALYSIS LETTERS, 1996, 42 (1-2) :93-97