A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase

被引：148

作者：

Bonnet, Sylvestre ^{[1
]}

Siegler, Maxime A. ^{[2
]}

Costa, Jose Sanchez ^{[1
]}

Molnar, Gabor ^{[3
]}

Bousseksou, Azzedine ^{[3
]}

Spek, Anthony L. ^{[2
]}

Gamez, Patrick ^{[1
]}

Reedijk, Jan ^{[1
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

[3] CNRS, Chim Coordinat Lab, UPR 8241, F-31077 Toulouse, France

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 43期

关键词：

D O I：

10.1039/b811746b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two-step spin crossover of a new mononuclear iron(II) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS-LS-LS] motif.

引用

页码：5619 / 5621

页数：3

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