Asymmetric nitrone-vinyl sulfoxide cycloadditions

被引：57

作者：

Louis, C ^{[1
]}

Hootele, C ^{[1
]}

机构：

[1] FREE UNIV BRUSSELS,FAC SCI,ORGAN CHEM DEPT CP16006,B-1050 BRUSSELS,BELGIUM

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 01期

关键词：

D O I：

10.1016/S0957-4166(96)00480-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cycloaddition of (Z) and (E)-vinyl sulfoxides with cyclic nitrones 1 and 2 is reported. Best diastereoselection is achieved with (Z)-vinyl sulfoxides 7a-d as dipolarophiles. This methodology allows the highly stereoselective synthesis of (+)-sedridine 9a, (-)-hygroline 10 and (-)-(2S)-N-carbomethoxypelletierine 11a. (C) 1997, Elsevier Science Ltd. All rights reserved.

引用

页码：109 / 131

页数：23

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