Cu Titration in CuInSe2: Exploration of the Ternary Phase Diagram along New Tie-Lines

被引：9

作者：

Jean, M. ^{[1
]}

Peulon, S. ^{[1
]}

Guillemoles, J. -F. ^{[1
]}

Vedel, J. ^{[1
]}

机构：

[1] ENSCP, Lab Electrochim, F-75005 Paris, France

来源：

IONICS | 1997年 / 3卷 / 1-2期

关键词：

Physical Chemistry; Analytical Chemistry; Phase Diagram; Titration; Solid State;

D O I：

10.1007/BF02375539

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using a CuInSe(2)/Cu(4)RbCl(5)/Cu solid state galvanic cell, we have studied the insertion and extraction of Cu in the host lattice of CuInSe(2). This allows to present the first experimental measurements of the formation energies of Cu-related point defects. Preliminary experiments on Cu insertion explore the possibility to obtain new thermodynamic information.

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页码：149 / 154

页数：6

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