Efficient and enantioselective nitroaldol reaction catalyzed by copper Schiff-base complexes

被引：103

作者：

Gan, CS

Lai, GY

Zhang, ZH

Wang, ZY

Zhou, MM ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[3] NYU, Mt Sinai Sch Med, Dept Physiol & Biophys, Struct Biol Program, New York, NY 10029 USA

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 05期

基金：

中国国家自然科学基金; 美国国家卫生研究院;

关键词：

D O I：

10.1016/j.tetasy.2006.01.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mild and efficient enantioselective nitroaldol reactions of nitromethane with various aldehydes were catalyzed by chiral copper Schiff-base complexes, which can be readily prepared from amino acid, yielding the corresponding adducts with high yields and good enantiometric excess (ee). (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：725 / 728

页数：4

共 36 条

[11] Asymmetric Henry reaction catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) complexes:: Metal-controlled reversal of enantioselectivity
Du, DM
Lu, SF
Fang, T
Xu, JX
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (09) : 3712 - 3715
[12] A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction
Evans, DA
Seidel, D
Rueping, M
Lam, HW
Shaw, JT
Downey, CW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (42) : 12692 - 12693
[13] Gademann K, 2002, ANGEW CHEM INT EDIT, V41, P3059, DOI 10.1002/1521-3773(20020816)41:16<3059::AID-ANIE3059>3.0.CO
[14] 2-I
[15] A study of substituent effects on the enantioselective trimethylsilylcyanation of benzaldehyde catalyzed by chiral Schiff base-titanium(IV) complexes
Gama, A
Flores-López, LZ
Aguirre, G
Parra-Hake, M
Somanathan, R
Cole, T
[J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (06) : 1167 - 1174
[16] Highly efficient chiral copper Schiff-base catalyst for asymmetric cyclopropanation of 2,5-dimethyl-2,4-hexadiene
Itagaki, M
Hagiya, K
Kamitamari, M
Masumoto, K
Suenobu, K
Yamamoto, Y
[J]. TETRAHEDRON, 2004, 60 (36) : 7835 - 7843
[17] Highly enantio- and regioselective quinone Diels-Alder reactions catalyzed by a tridentate [(Schiff base)CrIII] complex
Jarvo, ER
Lawrence, BM
Jacobsen, EN
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (37) : 6043 - 6046
[18] Activation of nitroaldol reactions by diethylzinc and amino alcohols or diamines as promoters
Klein, G
Pandiaraju, S
Reiser, O
[J]. TETRAHEDRON LETTERS, 2002, 43 (42) : 7503 - 7506
[19] Enantioselective Henry reaction catalyzed by optically active ketoiminatocobalt complexes
Kogami, Y
Nakajima, T
Ashizawa, T
Kezuka, S
Ikeno, T
Yamada, T
[J]. CHEMISTRY LETTERS, 2004, 33 (05) : 614 - 615
[20] Neutral zinc(II) and molybdenum(0) complexes with chiral guanidine ligands:: synthesis, characterisation and applications
Köhn, U
Schulz, M
Görls, H
Anders, E
[J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (12) : 2125 - 2131

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