Mophologies of vesicular silica templated by cationic surfactant with the auxiliary of diethyl ether

被引:17
作者
Cui, K [1 ]
Cai, Q [1 ]
Chen, XH [1 ]
Feng, QL [1 ]
Li, HD [1 ]
机构
[1] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
multi-lamellar structured silica vesicles; diethyl ether; self-assembly;
D O I
10.1016/j.micromeso.2003.11.014
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Mesoporous silica vesicles with controllable morphologies are successfully synthesized by the sol-gel method. The multi-lamellar structured products were obtained through assembly between a single-chain cationic surfactant of hexadecyltrimethyl ammonium bromide (CTAB) and silica precursors under the auxiliary of proper amount of diethyl ether. Snail-like, star-like and sharp-edged bowl-like morphologies were observed separately in the synthesized silica vesicles with the concentration of diethyl ether increased. The synthesis procedure provides a simple method to prepare vesicle-like materials. (C) 2003 Elsevier Inc. All rights reserved.
引用
收藏
页码:61 / 64
页数:4
相关论文
共 22 条
[1]   Surfactant-templated silica mesophases formed in water:cosolvent mixtures [J].
Anderson, MT ;
Martin, JE ;
Odinek, JG ;
Newcomer, PP .
CHEMISTRY OF MATERIALS, 1998, 10 (01) :311-321
[2]   Hierarchically mesoporous/macroporous metal oxides templated from polyethylene oxide surfactant assemblies [J].
Blin, JL ;
Léonard, A ;
Yuan, ZY ;
Gigot, L ;
Vantomme, A ;
Cheetham, AK ;
Su, BL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (25) :2872-2875
[3]   Dilute solution routes to various controllable morphologies of MCM-41 silica with a basic medium [J].
Cai, Q ;
Luo, ZS ;
Pang, WQ ;
Fan, YW ;
Chen, XH ;
Cui, FZ .
CHEMISTRY OF MATERIALS, 2001, 13 (02) :258-263
[4]   Silica hollow spheres by templating of catanionic vesicles [J].
Hentze, HP ;
Raghavan, SR ;
McKelvey, CA ;
Kaler, EW .
LANGMUIR, 2003, 19 (04) :1069-1074
[5]   Synthesis of titanium-containing MCM-41 mesoporous molecular sieves in the presence of zinc phthalocyanine and rhodamine B [J].
Hoppe, R ;
Ortlam, A ;
Rathousky, J ;
SchulzEkloff, G ;
Zukal, A .
MICROPOROUS MATERIALS, 1997, 8 (5-6) :267-273
[6]  
Hubert DHW, 2000, ADV MATER, V12, P1286, DOI 10.1002/1521-4095(200009)12:17<1286::AID-ADMA1286>3.0.CO
[7]  
2-7
[8]  
JONSSON B, 1998, SURFACTANTS POLM AQU, P84
[9]   The origins of stability of spontaneous vesicles [J].
Jung, HT ;
Coldren, B ;
Zasadzinski, JA ;
Iampietro, DJ ;
Kaler, EW .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (04) :1353-1357
[10]   Novel vesicular aggregates of crown-appended cholesterol derivatives which act as gelators of organic solvents and as templates for silica transcription [J].
Jung, JH ;
Ono, Y ;
Sakurai, K ;
Sano, M ;
Shinkai, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (36) :8648-8653