Confined Polymerization in Porous Organic Frameworks with an Ultrahigh Surface Area

被引：68

作者：

Comotti, Angiolina ^{[1
]}

Bracco, Silvia ^{[1
]}

Mauri, Martino ^{[1
]}

Mottadelli, Sergio ^{[1
]}

Ben, Teng ^{[2
]}

Qiu, Shilun ^{[2
]}

Sozzani, Piero ^{[1
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, Milan, Italy

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期

关键词：

host-guest systems; ladder polymers; microporous materials; nanostructures; polymerization; AROMATIC FRAMEWORK; SOLID-STATE; POLYMERS; SILICA; CONFORMATION; NETWORKS; DYNAMICS; POROSITY;

D O I：

10.1002/anie.201205618

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Polymers framed: Interpenetrated nanocomposites were formed by polymerization of acrylonitrile in a ultrahigh surface area (>5000 m 2 g -1) porous framework. The resulting material realizes a hyperextended interface with uniform interdigitation of the two structures at the size limit of the individual molecular moieties. The confined poly(acrylonitrile) chains could be transformed into light-absorbing polyconjugated ladder polymers. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：10136 / 10140

页数：5

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