Electrospinning lead-free 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 nanowires and their application in energy harvesting

被引:93
作者
Wu, Weiwei [1 ]
Cheng, Li [1 ]
Bai, Suo [1 ]
Dou, Wei [1 ]
Xu, Qi [1 ]
Wei, Zhiyang [1 ]
Qin, Yong [1 ,2 ]
机构
[1] Lanzhou Univ, Inst Nanosci & Nanotechnol, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100085, Peoples R China
关键词
ZIRCONATE-TITANATE; SINGLE-CRYSTALS; PIEZOELECTRIC PROPERTIES; BARIUM-TITANATE; PHASE; NANOGENERATOR; TEMPERATURE; CERAMICS; BEHAVIOR; ALLOYS;
D O I
10.1039/c3ta10792b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High performance nanogenerators (NGs) are critically important for energy harvesting and powering micro/nano-devices. Environmentally friendly nanowires (NWs) with high piezoelectric coefficients are highly desirable for enhancing NGs' performance and expanding their applications. In this paper, we synthesized a new kind of lead-free 0.5Ba(Zr0.2Ti0.8)O-3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) NWs with high piezoelectric coefficients through the electrospinning method and subsequent calcining process. Their crystal structure and formation mechanism were systematically studied. Furthermore, BZT-BCT NWs were made into a high performance flexible NG. It could harvest weak mechanical movement energy and generate an output voltage of 3.25 V and output current of 55 nA, which is large enough to directly power a commercial liquid crystal display (LCD).
引用
收藏
页码:7332 / 7338
页数:7
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