Synthesis of variable-aspect-ratio, single-crystalline ZnO nanostructures

被引：94

作者：

Cheng, B

Shi, WS

Russell-Tanner, JM

Zhang, L

Samulski, ET ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

[2] Univ N Carolina, Curriculum Appl Mat Sci, Chapel Hill, NC 27599 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 03期

关键词：

D O I：

10.1021/ic051786a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Variable-aspect-ratio (length/diameter), one-dimensional (1-D) ZnO nanostructures (nanorods and nanowires) were prepared in alcohol/water solution by reacting a Zn2+ precursor with an organic weak base, tetramethylammonium hydroxide (Me4NOH). The effect of the experimental parameters (temperature, base concentration, reaction time, and water content) on nucleation, growth, and the final morphology of the ZnO nanostructures was investigated. The low-temperature syntheses (75-150 degrees C) yielded aspect ratios of the 1-D ZnO nanostructures that depended on the water content. The individual ZnO nanorods and nanowires were determined to be perfect, single crystals with their c axes as the primary growth direction.

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页码：1208 / 1214

页数：7

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